Destructive tests


Sat 19 January 2013

Stave xxx-01 is one of the bad leakers, though we were not able to precisely pinpoint the location.

I milled away the carbon face sheet, you can see some of the thin foam remaining on the tube on the right of the worked area. Then I milled away the top surface of the Al tube, and cleaned the burrs.

The inside surfaces are pristine, no marks of any kind.



A picture taken through Sal's microscope also does not reveal any more details. (The two green spots on the left are markers in the microscope optics).
I cut 4 pieces of the carbon foam, and 4 pieces of G4, and assembled 4 Aluminum-Carbon sandwiches. I used one of the tubes from LBL, not the new straight tubes we bought.
I immersed the assemblies in tap water. Start time Sat 19 January 2013, 13:00. We have to decide when to remove each of the samples (Perhaps 1st in 1 week, 2nd in 2 weeks, 3rd in 4 weeks, 4th in 8 weeks).
In order to speed up the corrosion, Walter suggested to pass a current trough the Al-C interface. So I made a sansdwich of a carbon foam stick with a piece of Al tube,
I hooked up 2 versions, with a 24 ohm resistor in series with a 1.5 V battery:
  1. +1.5V connected to the carbon - Start 16:00, initial current 45.7 mA.
  2. +1.5V connected to the Al - Start 16:30, initial current 42.5 mA)
 
On Tuesday, the currents were still roughly the same, but whitish stuff had appeared at the carbon/Al interface. This is very weak stuff, which detaches and floats to the bottom when the fluid moves a little.
 


The small tube samples were mounted such that they coul be handled without touching them, as there was some of the white stuff on various surfaces. As this dried out, it turned into whitish crystals, which can be seen in some of the frames.
blue/red:

segment side facing carbon side facing water

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4

green/red:

segment side facing carbon side facing water

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4



Next the passive sample was scanned front and back. Note the water-facing side is clean, and the carbon-facing side shows corrosion. Segment 8 is where the water surface was, and there is action on both sides, probably due to the presence of both water and oxygen.

segment facing carbon facing water

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Hubert Van Hecke
Last modified: Fri Feb 1 00:02:06 EST 2013